[1]唐丽娟,赵跃强,许瑞波,等.香草醛-苯硫羰基腙化合物的合成[J].华侨大学学报(自然科学版),2009,30(3):289-291.[doi:10.11830/ISSN.1000-5013.2009.03.0289]
　TANG Li-juan,ZHAO Yue-qiang,XU Rui-bo,et al.Synthesis of Vanillin Benzylthiocarboxyhydrazone Compound[J].Journal of Huaqiao University(Natural Science),2009,30(3):289-291.[doi:10.11830/ISSN.1000-5013.2009.03.0289]
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香草醛-苯硫羰基腙化合物的合成()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第30卷
期数:
2009年第3期
页码:
289-291
栏目:
出版日期:
2009-05-20

文章信息/Info

Title:
Synthesis of Vanillin Benzylthiocarboxyhydrazone Compound
文章编号:
1000-5013(2009)03-0289-03
作者:
唐丽娟; 赵跃强; 许瑞波; 刘玮炜
淮海工学院化学工程学院
Author(s):
TANG Li-juan;  ZHAO Yue-qiang;  XU Rui-bo;  LIU Wei-wei
School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China
关键词:
硫羰基腙;  苯硫酰肼;  香草醛;  表征
Keywords:
thiocarboxyhydrazone;  benzylthiohydrazide;  vanillin;  characterization
分类号:
O641.4
DOI:
10.11830/ISSN.1000-5013.2009.03.0289
文献标志码:
A
摘要:
以苯甲醛、多硫化铵及水合肼为原料合成苯硫酰肼,研究苯硫酰肼与香草醛的反应,合成出新型的,含"NCS"基团的非缩氨基硫脲化合物——香草醛-苯硫羰基腙.通过红外光谱分析,证实了苯硫酰腙化合物结构中硫羰腙基团的存在,表明苯甲醛硫酰肼与香草醛的合成反应是成功的; 通过质谱分析得出香草醛苯硫羰基腙化合物出现分子离子峰,碎片离子峰的质荷比(m.z-1)分别为286,284,163,150,137,121,103,78等,而基峰质荷比为137,数据与预期的目标化合物吻合较好.
Abstract:
In this paper benzylthiohydrazide was prepared from benzaldehyde,ammonium polysnlphide solution and hydrazine hydrate.The reaction of benzylthiohydrazide and vanillin was studied,and the new non-thiosemicarbazone compound with "NCS" group was achieved.The thiocarboxyhydrazone group are confirmed to exist at the benzylthioacylhydrazone compound by Fourier transform infrared(FTIR).And the result shows that the reaction of benzylthiohydrazide and vanillin are sucessful.In mass spectrometry of the vanillin benzylthiocarboxyhydrazone compound,the molecular ion and the characteristic fragment ion were observed at m·z-1 286,284,163,150,137,121,103,78 and the base peak at m·z-1 137.The above experimental results are consistent with the target compound.

参考文献/References:

[1] SINGH R K, STOFFER J O, FLAIM T D. Monohydroxy-hydrazone-functionalized thermally-crosslinked poly-mers for nonlinear optics [J]. Journal of Applied Polymer Science, 2004(2):770-781.doi:10.1002/app.13309.
[2] CERCHIARO G, FERREIRA A M C. Oxindoles and copper complexes with oxindole-deriva-tivesas potential pharmacological agents [J]. Journal of the Brazilian Chemical Society, 2006(8):1473-1485.
[3] 葛蔚颖, 徐丽君. 2-呋喃硫羰基腙衍生物及其过渡金属配位化合物的合成和抑菌活性 [J]. 药学学报, 1989(1):27-31.
[4] 葛小鹏, 张宝文, 王锡宁. 大孔聚丙烯醛-呋喃-2-硫代酰腙螫合树脂的合成及其性能的初步研究 [J]. 离子交换与吸附, 2003(2):111-120.doi:10.3321/j.issn:1001-5493.2003.02.003.
[5] 李晓荣, 樊锁强. 硫代酰腙及其金属配合物的红外光谱性质 [J]. 陕西师范大学学报(自然科学版), 1990(2):93-94.

备注/Memo

备注/Memo:
国家自然科学基金资助项目(20672090); 江苏省教育厅自然科学基金资助项目(08KJB150002); 江苏省“六大人才”高峰基金资助项目(07-A-024); 连云港市科技攻关计划项目(CG0803-2)
更新日期/Last Update: 2014-03-23